吳凱[北京大學理學部副主任]

吳凱[北京大學理學部副主任]

北京大學理學部副主任 、化學與分子工程學院長江學者特聘教授 、博士生導師,歷任北京大學物理化學研究所所長、化學與分子工程學院院長。2001年國家傑出青年基金獲得者,2009年長江學者特聘教授。1995年獲中科院自然科學三等獎。迄今在Science、Nature、J. Am. Chem. Soc.、Adv. Mater.等學術期刊發表論文近七十篇;作為客座編輯之一為Adv. Mater.、Coord. Chem. Rev.、Chem. - Asian J.及《物理化學學報》等刊物編輯專刊四期;在國內外學術會議和機構做特邀和邀請報告五十餘場次。

基本信息

學術簡歷

1983-1987,浙江大學,理學學士學位

1987-1991,中國科學院大連化學物理研究所,理學博士學位

1992-1995,大連化物所催化基礎國家重點實驗室,助理/副研究員

1995-1998,德國馬普協會Fritz-Haber研究所,訪問科學家

1998-2000,美國能源部太平洋西北國家實驗室,博士後

2000-至今,北京大學化學與分子工程學院,教授

獲獎情況

1995年,中科院自然科學三等獎

2001年,國家傑出青年基金獲得者

2008年,北京大學寶潔獎教金

2009年,教育部長江學者特聘教授

2017年,北京大學本科教學優秀獎

學術兼職

Advanced Functional Materials顧問編委

《物理化學學報》、《催化學報》、《化學學報》和《科學通報》等編委

第十三屆“中國化學會全國催化委員會”委員

中國化學會物理化學委員會委員

中國物理學會“表面與界面委員會”委員

中國物理學會“表面與界面委員會”委員

中科院化學所兼職研究員

南京工業大學兼職教授

表面物理與化學重點實驗室兼職研究員

新加坡國立大學 Distinguished Visiting Professor

主講課程

《表面結構與表面分析》(研究生專業選修課,01年至03年)

《表征技術》(全院研究生基礎課,04年至07年)

《表面物理化學》(研究生專業選修課,05年至今)

《物理化學》(化學學院本科生必修課,2008-2016年)

《興大報告》(化學學院研究生必修課,2015年起)

《物理化學》(化學學院本科生必修課,小班教學,2017年起)

研究興趣

利用表面和界面的結構、反應性和周期性來控制分子/原子簇的組裝和功能材料的表面生長。表面結構也可用於調節表面電子性質,進而調變分子的吸附和活化。人們也可以通過設計新的表面結構來控制和調節分子的表面吸附與活化,此之謂化學反應的表面調節。這些研究對於表面反應調節、表面配位、表面圖案化與加工、能量轉換等具有重要的意義。

利用功能分子的自組裝在表面上產生有序圖案。這些分子通常通過范德華力、氫鍵、靜電相互作用、偶極作用以及配位作用而聚集在一起。經過一定的功能化處理,金屬原子/離子可以被引入到各種表面分子結構中,它們的電子自旋及相互作用就可以通過這些結構的對稱性、配位數和金屬原子/離子間距的改變而得到調控。這對於研究電子自旋相關的現象具有重要的學術價值。

研究方向

1) 納米功能材料的表面生長與控制;

2) 納米晶體的表面性質;

3) 固體表面的分子非催化活化;

4) 分子自組裝與組裝調控的化學反應;

5) 表面上的電子自旋狀態的設計、控制與利用

論文選列

X. Zhou, C.G. Wang, Y. J. Zhang, F. Cheng, Y. He, Q. Shen, J. Shang, X. Shao, W. Ji, W. Chen, G. Q. Xu, K. Wu, “Steering Surface Reaction Dynamics with a Self-Assembly Strategy: Ullmann Coupling on Metal Surfaces”, Angew. Chem. Int. Ed., 2017, in press.

X. Zhou, F. Bebensee, M. M. Yang, R. Bebensee, F. Cheng, Y. He, Q. Shen, J. Shang, Z. R. Liu, F. Besenbacher, T. R. Linderoth, K. Wu, “Steering Surface Reaction at Specific Sites with a Self-Assembly Strategy”, ACS Nano, 2017, in press.

Q. W. Chen, J. R. Cramer, J. Liu, X. Jin, P. L. Liao, X. Shao, K. V. Gothelf, K. Wu, “Steering On-Surface Reaction with a Self-Assembly Approach”, Angew. Chem. Int. Ed., 56 (2017) 5026.

Z. C. Huang, Y. J. Zhang, Y. He, H. J. Song, C. Yin, K. Wu, “A chemist’s overview of surface electron spins”, Chem. Soc. Rev., 46 (2017) 1955.

M. Chen, J. Shang, Y. F. Wang, K. Wu, J. Kuttner, G. Hilt, W. Hieringer, J. M. Gottfried, “On-Surface Synthesis and Characterization of Honeycombene Oligophenylene Macrocycle”, ACS Nano, 11 (2017) 134.

S. Karan, N. Li, Y.J. Zhang, Y. He, I.-P. Hong, H. J. Song, J.-T. Lu, Y. F. Wang, L. M. Peng, K. Wu, G. S. Michelitsch, R. J. Maurer, K. Diller, K. Reuter, A. Weismann, R. Berndt, “Spin Manipulation by Creating Single-Molecule Radical Cations”, Phys. Rev. Lett., 116 (2016) 027201.

J. Shang, Y.F. Wang, M. Chen, J.X. Dai, X. Zhou, J. Kuttner, G. Hilt, X. Shao, J. M. Gottfried, K. Wu, “Assembling Molecular Sierpiński Triangle Fractals”, Nature Chemistry, 7 (2015) 389 (Cover).

X. Zhang, N. Li, G.-C. Gu, H. Wang, D. Nieckarz, P. Szabelski, Y. He, Y. Wang, C. Xie, Z.Y. Shen, J.-T. Lu, H. Tang, L.-M. Peng, S.-M. Hou, K. Wu, Y.F. Wang, “Controlling Molecular Growth between Fractals and Crystals on Surfaces”, ACS Nano, 9 (2015) 11909.

J. Liu, Q. W. Chen, L. H. Xiao, J. Shang, X. Zhou, Y. J. Zhang, Y. F. Wang, X. Shao, J. L. Li, W. Chen, G. Q. Xu, H. Tang, D. H. Zhao, K. Wu, “Lattice-Directed Formation of Covalent and Organometallic Molecular Wires by Terminal Alkynes on Ag Surfaces”, ACS Nano, 9 (2015) 6305.

H. T. Xu, H.J. Zhang, L. Fang, J. Yan, K. Wu, Y. Wang, “Hierarchical Molybdenum Nitride Nanochexes by a Textured Self-Assembly in Gas-Solid Phase for the Enhanced Application in Lithium Ion Batteries”, ACS Nano, 9 (2015) 6817.

J. Yin, J. Yan, M. He, Y.L. Song, X.G. Xu, K. Wu, and J. Pei, “Solution-Processable Flower-Shaped Hierarchical Structures: Self-Assembly, Formation, and State Transition of Biomimetic Superhydrophobic Surfaces”, Chemistry - A European Journal, 2010, in press.

J.F. Yu, Y. Wang, W. Wen, D.H. Yang, B. Huang, J.L. Li, and K. Wu, “Aluminothermal Reaction Approach for Micro/Nanofabrications: Syntheses of In2O3 micro/nanostructures and InN octahedral nanoshells”, Advanced Materials, 22 (2010) 1479.

J.F. Yu, F. Wang, Y. Wang, H. Gao, J.L. Li and K. Wu, “Interfacial Reaction Growth Approach to Preparing Patterned Nanomaterials and Beyond”, Chemical Society Reviews, 39 (2010) 1513.

H.L. Liang, Y. He, Y.C. Ye, X.G. Xu, F. Cheng, W. Sun, X. Shao, Y.F. Wang, J.L. Li and K. Wu, “Two-dimensional Molecular Porous Networks Constructed by Surface Assembling”, Coordination Chemistry Reviews, 253 (2009) 2959.

X.G. Xu, J. Yin, H. Li, Y. Zhou, J.L. Li, J. Pei and K. Wu, “Self-assembly of Benzodithiophene Derivatives on Graphite: Effects of Substitution Alkoxy Chain Number and Location”, Journal of Physical Chemistry C, 113 (2009) 8844.

R.C. Bell, K. Wu, M.J. Iedema, G.K. Schenter and J.P. Cowin, “The Oil-Water Interface: Mapping the Solvation Potential”, Journal of American Chemical Society, 131 (2009) 1037.

F. Wang, Y. Wang, J.F. Yu, Y.C. Xie, J.L. Li and K. Wu, “Template-assisted Preparations of Crystalline Mo and Cu Nanonets”, Journal of Physical Chemistry C, 112 (2008) 13121.

S.N. Qu, X.F. Chen, X. Shao, F. Li, H.Y. Zhang, H.T. Wang, P. Zhang, Z.X. Yu, K. Wu, Y. Wang and M. Li, “Self-assembly of highly luminescent bi-1,3,4-oxadiazole derivatives through electron donor–acceptor interactions in three-dimensional crystals, two-dimensional layers and mesophases”, Journal of Materials Chemistry, 18 (2008) 3954.

H.F. Wang, R.C. Bell, M.J. Iedema, G.K. Schenter, K. Wu and J.P. Cowin, “Pyroelectricity of Water Ice”, Journal of Physical Chemistry B, 112 (2008) 6379.

J. Luo, T. Lei, X.G. Xu, F.M. Li, Y.G. Ma, K. Wu, and J. Pei, “Three-Dimensional Shape-Persistent Fluorescent Nanocages: Facile Dynamic Synthesis, Photophysical Properties, and Surface Morphologies”, Chemistry- A European Journal, 14 (2008) 3860.

R. C. Bell, K. Wu, M. J. Iedema and J. P. Cowin, “Hydronium Ion Motion in Nanometer 3-methylpentane Films”, Journal of Chemical Physics, 127 (2007) 024704.

Q. Liao, Y. Wang, J.L. Li, K. Wu, X.-C. Ai, and J.-P. Zhang, “Spatially Confined Light Output of a Crystalline Zinc Oxide Nanonet Laser”, Applied Physics Letters, 91 (2007) 041103.

Y.C. Ye, W. Sun, Y.F. Wang, X. Shao, X.G. Xu, F. Cheng, J.L. Li and K. Wu, “A Unified Model: Self-Assembly of Trimesic Acid on Gold”, Journal of Physical Chemistry C, 2007, 111, 10138 (Cover Paper).

X. Shao, X.C. Luo, X.Q. Hu and K. Wu, “Chain-Length Effects on Molecular Conformation in and Chirality of Self-Assembled Monolayers of Alkoxylated Benzo[c]cinnoline Derivatives on Highly Oriented Pyrolytic Graphite”, Journal of Physical Chemistry B, 110 (2006) 15393.

Y.F. Wang, Y.C. Ye and K. Wu, “Adsorption and Assembly of Copper Phthalocyanine on Cross-linked TiO2(110)-(1×2) and TiO2(210)”, Journal of Physical Chemistry B, 110 (2006) 17960.

T.G. Xu, C. Zhang, X. Shao, K. Wu, Y.F. Zhu, “Monomolecular-Layer Ba5Ta4O15 Nanosheets: Synthesis and Investigation of Photocatalytic Properties”, Advanced Functional Materials, 16 (2006) 1599.

Y. Wang, Q. Liao, H. Lei, X.P. Zhang, X.C. Ai, J.P. Zhang, K. Wu, “Interfacial Reaction Growth: Morphology, Composition and Structure Controls in Preparation of Crystalline ZnxAlyOz Nanonets”, Advanced Materials, 18 (2006) 943.

X. Shao, X.C. Luo, X.Q. Hu and K. Wu, “Solvent Effect on Self-assembled Structures of 3,8-Bis-hexadecyloxy-benzo[c]cinnoline on Highly Oriented Pyrolytic Graphite”, Journal of Physical Chemistry B, 110 (2006) 1288.

Y.F. Wang, Y.C. Ye and K. Wu, “Simultaneous Observation of the Triangular and Honeycomb Structures on Highly Oriented Pyrolytic Graphite at Room Temperature: an STM Study”, Surface Science, 600 (2006) 729.

X.R. Zhang, Y.F. Wang, Y. Ma, Y.C. Ye, Y. Wang and K. Wu, “Solvent-stabilized Oxovanadium Phthalocyanine Nanoparticles and Their Application in Xerographic Photoreceptors”, Langmuir, 22(2006)344.

Y. Wang and K. Wu, “As a Whole: Crystalline Zinc Aluminate Nanotube Array – Nanonet”, Journal of American Chemical Society, 127 (2005) 9686.

C. Mu, Y.X. Yu, R.M. Wang, K. Wu, D.S. Xu and G.L. Guo, “Uniform Metal Nanotube Arrays by Multi-step Template Replication and Electrodeposition”, Advanced Materials, 16 (2004) 1550.

H. Gao, X.B. Wu, J.T. Li, G.T. Wu, J.Y. Lin, K. Wu and D.S. Xu, “Hydrogen Adsorption of Open-Tipped Insufficiently Graphitized Multiwalled Carbon Nanotubes”, Applied Physics Letters, 83(2003) 3389.

H. Gao, C. Mu, F. Wang, D.S. Xu, K. Wu, Y.C. Xie, S. Liu, E.G. Wang, J. Xu and D.P. Yu, “Field emission of large-area and graphitized carbon nanotube array on anodic aluminum oxide template”, Journal of Applied Physics, 93 (2003) 5602.

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